河南塔山萤石矿地球化学特征及成矿年龄     

张凯涛 《地质与勘探》2023,59(2):236-247

为探究河南塔山萤石矿的成矿流体、成矿温度、成矿年龄及矿床成因,对研究区稀土元素、流体包裹体和Sm-Nd同位素特征进行了研究。研究区经历多期次的成矿作用,紫色萤石形成时间较早,紫色萤石成矿早期成矿流体中的稀土元素由吸附状态逐渐过渡到络合物状态,成矿晚期成矿流体中的稀土元素主要以络合物形式存在,为主成矿阶段,其球粒陨石标准化稀土元素配分模式和Y/Ho值与牛心山黑云母二长花岗岩、大理岩基本一致,指示三者之间有一定的成因联系。浅绿色萤石形成时间相对较晚,其与紫色萤石的稀土元素配分模式差异较大,表明二者具有不同成矿物质来源。塔山萤石矿发育气液两相包裹体,包裹体均一温度为143.6～168.5℃,盐度(NaCl_eqv)为7.02%～10.43%,密度为0.95～1.01 g/cm³;包裹体气-液相成分以H₂O为主,含有少量C₂H₆,成矿流体属于低温、中低盐度、低密度的NaCl-H₂O体系。测得的浅绿色萤石的成矿年龄为(141±13)Ma,为研究区萤石成矿年龄上限,推断...  相似文献   

大兴安岭北段喀喇其花岗斑岩体地球化学特征、锆石U-Pb年龄及构造背景          下载免费PDF全文

洪文武 《地质找矿论丛》2023,38(2):209-214

本文对大兴安岭北部喀喇其花岗斑岩体进行了岩石学、地球化学及锆石U-Pb年代学的研究,探讨了其形成的构造背景。结果表明:喀喇其花岗斑岩体锆石U-Pb年龄为132 Ma±1 Ma,表明其形成时代应为早白垩世晚期;岩石具有高钾钙碱性系列,过铝质特征;稀土元素属于轻稀土富集型,分布模式为右倾、左陡右平型式,具有较明显的Eu负异常特征。认为该花岗岩为铝质A型花岗岩,属于地壳岩石部分熔融的产物;该期岩浆侵位活动受蒙古—鄂霍茨克构造体系影响,形成于后造山大陆弧或后碰撞弧环境。  相似文献   

滇西马厂箐铜钼多金属矿床成矿流体来源及演化过程——来自石榴子石原位微量元素及H- O同位素组成的限定     

吉彦冰  杜丽娟  陈军  黄智龙  李波  李鑫正  刘林林  杨再风 《地质学报》2023,97(4):1140-1156

滇西马厂箐铜钼多金属矿床位于三江特提斯成矿域,是一个与喜马拉雅期富碱斑岩侵入有关的多金属矿床。前人研究表明,马厂箐铜钼多金属矿床形成于斑岩-矽卡岩成矿系统,但由于缺乏系统矿物学研究,目前对矽卡岩矿化过程和成矿效应仍不清楚,限制了对该矿床成矿过程的全面认识。因此,本文以马厂箐矿床矽卡岩型矿化中的石榴子石为研究对象,利用H-O同位素、电子探针(EPMA)以及LA-ICP-MS原位微区技术开展了同位素及成分分析,限定成矿流体来源以及反演成矿流体演化过程。石榴子石可分为早期自形石榴子石(Grt I)和晚期他形石榴子石(Grt II)。Grt I与辉石共生,并伴有黄铁矿、黄铜矿等金属矿物组合,属于钙铝-钙铁榴石固溶体(And_{49.37～99.58}Gro_0～49.79);Grt II更富Fe,属钙铁榴石系列(And_{67.50～99.85}Gro_0～31.84)。两期石榴子石均富含Th、U、Nd,亏损Ba、Sr、Hf、Nb,富轻稀土。基于石榴子石矿物化学特征认为,Grt I可能是在弱酸性、氧化、低水岩比(W/R)条...  相似文献   

铜锡复合成矿研究进展与展望     

李欢  吴经华  孙文博  刘飚 《地质学报》2023,97(1):262-277

铜与锡具有不同的地球化学性质,然而铜锡共生或复合成矿现象在世界主要铜、锡成矿带中比较常见,如中国的右江、南岭(湘南)、大兴安岭南段(内蒙东部)、葡萄牙伊比利亚、秘鲁安第斯、英格兰德文郡、德国厄尔士山、日本西南、俄罗斯远东、加拿大新不伦瑞克等成矿带均为铜锡复合矿床的集中产区。铜锡复合矿床主要为岩浆热液矿床,以矽卡岩型、脉状矿床为主,兼有火山热液沉积型、斑岩型及云英岩型等。铜矿体的主要矿石矿物为黄铜矿,兼有斑铜矿、黝铜矿、辉铜矿等;锡矿体的主要矿石矿物为锡石,兼有黝锡矿。铜锡复合矿床的成矿物质来源(尤其是铜、锡成矿元素的来源是否具有一致性)尚有不少争议,锡普遍被认为是岩浆来源,而铜的来源具有多样性。成矿流体演化过程中的氧化还原环境的改变及流体的混合是导致铜锡复合成矿的主要原因。目前对于铜锡复合成矿的研究,主要是从矿床的年代学、单矿物(黄铜矿、锡石)微量元素及传统同位素地球化学、流体包裹体等方面入手,但对厘定铜锡复合成矿过程的作用有限。铜锡复合矿床的成因及勘查模型的建立具有重要的理论价值及现实意义。本文提出未来研究可以从多种非传统稳定同位素(例如Cu、Sn、W、Zn同位素)的联合示踪探索、成...  相似文献   

江西德兴铜矿田成矿热液演化过程及其对铼差异性富集的制约     

陈涛亮  任志  冷成彪  王安东 《地质学报》2023,97(6):1900-1916

铜厂和富家坞矿床是德兴矿田中两个典型的斑岩铜矿床,二者成矿时代、成矿背景和致矿斑岩均较一致,但前者中辉钼矿的Re含量明显高于后者。为探究成矿流体演化过程对辉钼矿中Re含量差异的影响,本文对铜厂和富家坞不同成矿阶段的石英开展LA- ICP- MS微区原位分析以及流体包裹体测温研究。结果显示,二者流体均具有由高温向低温,中低盐度高盐度共存向低盐度演化的趋势,且温度下降、流体沸腾以及pH值的变化可能是导致Cu、Mo沉淀的主要原因;但就同一成矿阶段而言,铜厂比富家坞成矿温度更低,并且在主成矿阶段,铜厂具有更高的流体盐度;因此,推测温度和盐度可能是导致二者中辉钼矿Re含量差异的主导因素。  相似文献   

河南省内乡县银洞沟银金多金属矿成矿年龄: 热液锆石LA-MC-ICP-MS U-Pb测年     

曾威  王佳营  涂家润  李志丹  胡鹏  李光耀  许雅文  叶丽娟 《地质学报》2023,97(6):1972-1986

北秦岭构造带广泛发育与古生代洋壳俯冲和碰撞造山有关的岩浆活动以及与造山过程有关的变质作用,但古生代热液脉型矿床在北秦岭构造带少见报道。银洞沟银金多金属矿为北秦岭构造带东部的一处中型热液脉型矿床,本文通过对该矿床赋矿围岩和含矿石英脉中锆石开展LA- MC- ICP- MS U- Pb测年和锆石成因研究,确定了矿床的形成时代,并探讨了矿床的成矿动力学背景。结果表明赋矿围岩黑云母二长花岗岩的形成时代为431. 4±2. 1 Ma,含矿石英脉中锆石结晶年龄为419. 4±5. 9 Ma,石英脉中锆石的岩相学、锆石中矿物和流体包裹体及锆石微量元素研究表明419. 4 Ma代表矿床的形成时代。结合前人的研究结果,确定银洞沟银金多金属矿为形成于晚志留世的造山型矿床,成矿作用与碰撞期后～420 Ma的变质作用密切相关,成矿流体来源于地层的变质脱水,成矿物质主要来源于秦岭岩群和二郎坪群。  相似文献   

Water mining from the deep critical zone by apple trees growing on loess     

Huijie Li  Bingcheng Si  Pute Wu  Jeffrey J. McDonnell 《水文研究》2019,33(2):320-327

There have been significant recent advances in understanding the ecohydrology of deep soil. However, the links between root development and water usage in the deep critical zone remains poorly understood. To clarify the interaction between water use and root development in deep soil, we investigated soil water and root profiles beyond maximum rooting depth in five apple orchards planted on farmland with stand ages of 8, 11, 15, 18, and 22 years in a subhumid region on the Chinese Loess Plateau. Apple trees rooted progressively deeper for water with increasing stand age and reached 23.2 ± 0.8 m for the 22‐year‐old trees. Soil water deficit in deep soil increased with tree age and was 1,530 ± 43 mm for a stand age of 22 years. Measured root deepening rate was far great than the reported pore water velocity, which demonstrated that trees are mining resident old water. The deficits are not replenished during the life‐span of the orchard, showing a one‐way mining of the critical zone water. The one‐way root water mining may have changed the fine root profile from an exponential pattern in the 8‐year‐old orchard to a relative uniform distribution in older orchards. Our findings enhance our understanding of water‐root interaction in deep soil and reveal the unintended consequences of critical zone dewatering during the lifespan of apple trees.  相似文献   

Snowpack disrupts relationship between young water fraction and isotope amplitude ratio; approximately one fifth of mountain streamflow less than one year old     

Éowyn M. S. Campbell  Igor Pavlovskii  M. Cathryn Ryan 《水文研究》2020,34(25):4762-4775

Previous “fraction of young water” (F_yw) estimates based on relative annual isotopic amplitudes in precipitation (A_p) and streamflow (A_s) produced low F_yw values in mountain catchments, which is contrary to extensive research that reports rapid water transmission in mountains. This study investigated this discrepancy by testing the effect of snow accumulation on the model that underpins the F_yw method. A Monte-Carlo analysis of simulations for 20,000 randomly-generated catchment model configurations used 10 years of precipitation inputs for the Upper Elbow River catchment in the Rocky Mountains (Alberta, Canada) to model discharge with and without snowpack storage of winter precipitation. Neither direct nor modified precipitation input produced a 1:1 relationship between A_s/A_p and F_yw, undermining the applicability of the original F_yw method in mountain watersheds with large seasonal snow accumulation. With snowpack-modified input a given A_s/A_p ratio corresponds to a range of F_yw values, which can still provide semi-quantitative information. In the small (435 km²) Elbow River catchment a F_yw range of 7–23% supports previous findings of rapid transmission in mountain catchments. Further analysis showed that the improved discharge prediction (Nash–Sutcliffe efficiency > 0.9) correlates with higher F_yw values and demonstrated that the interannual shifts in δ¹⁸O can be used to estimate of new water (<1 year) fraction in winter streamflow, and the estimate of 20% for the Elbow River further supports rapid transmission in mountain catchments.  相似文献   

Lagged rejuvenation of groundwater indicates internal flow structures and hydrological connectivity     

Tamara Kolbe  Jean Marçais  Jean-Raynald de Dreuzy  Thierry Labasque  Kevin Bishop 《水文研究》2020,34(10):2176-2189

Large proportions of rainwater and snowmelt infiltrate into the subsurface before contributing to stream flow and stream water quality. Subsurface flow dynamics steer the transport and transformation of contaminants, carbon, weathering products and other biogeochemistry. The distribution of groundwater ages with depth is a key feature of these flow dynamics. Predicting these ages are a strong test of hypotheses about subsurface structures and time-varying processes. Chlorofluorocarbon (CFC)-based groundwater ages revealed an unexpected groundwater age stratification in a 0.47 km² forested catchment called Svartberget in northern Sweden. An overall groundwater age stratification, representative for the Svartberget site, was derived by measuring CFCs from nine different wells with depths of 2–18 m close to the stream network. Immediately below the water table, CFC-based groundwater ages of already 30 years that increased with depth were found. Using complementary groundwater flow models, we could reproduce the observed groundwater age stratification and show that the 30 year lag in rejuvenation comes from return flow of groundwater at a subsurface discharge zone that evolves along the interface between two soil types. By comparing the observed groundwater age stratification with a simple analytical approximation, we show that the observed lag in rejuvenation can be a powerful indicator of the extent and structure of the subsurface discharge zone, while the vertical gradient of the age-depth-relationship can still be used as a proxy of the overall aquifer recharge even when sampled in the discharge zone. The single age stratification profile measured in the discharge zone, close to the aquifer outlet, can reveal the main structure of the groundwater flow pattern from recharge to discharge. This groundwater flow pattern provides information on the participation of groundwater in the hydrological cycle and indicates the lower boundary of hydrological connectivity.  相似文献   

鄱阳湖水龄季节性变化特征   总被引：3，自引：1，他引：2  

张素香  许新发  徐兴  CHU Vicnent H  邬年华  付莎莎  李熙 《湖泊科学》2018,30(1):199-210

基于环境水动力学模型EFDC源程序,建立了染色剂模型和水龄模型,在将模型与航测水文数据验证吻合的基础上,分别计算了鄱阳湖自然条件下春、夏、秋、冬季的水龄和倒灌前后鄱阳湖染色剂和水龄分布的变化,以及五河水系各分支河流水龄.分季节的水龄计算表明鄱阳湖水体交换受季节性来水影响明显.夏、秋季的水龄相对较小,在多数年份又受到长江水倒灌的影响导致水龄有所增大;冬、春季水龄较大,亦无长江水倒灌现象,相较于夏、秋季,水域面积明显减少.分支流的水龄计算表明,西南湖区的水体交换主要受到赣江的影响,西北湖区水体交换主要受到修水和赣江的影响,南部湖区主要受到抚河与信江的影响,东部湖区主要受到饶河的影响,湖心区和入江水道则受到五河水系的综合影响.同时水龄的研究表明拟建的鄱阳湖水利枢纽工程"调枯不调洪"的原则是合理的,为鄱阳湖水利枢纽工程论证提供了重要的参考依据.  相似文献